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Acetone MSDS |
M A T E R I A L S A F E T Y D A T A S H E E T |
MATERIAL SAFETY DATA SHEET 1 0Special Health Flammability Instability 05/18/2005 11/13/2008 03/13/2006 Date Created: Revision: Supercedes Revision: Printed: 12/30/2008 FLAMMABILITY HEALTH PPE PHYSICAL HAZ. 1 0 3 1. Product and Company Identification Product Code: 1640.1 Product Name: Klean-Strip Acetone Reference #: 1640.1 Manufacturer Information Company Name: W. M. Barr 2105 Channel Avenue Memphis, TN 38113 Phone Number: (901)775-0100 Emergency Contact: 3E 24 Hour Emergency Contact (800)451-8346 Information: W.M. Barr Customer Service (800)398-3892 Web site address: www.wmbarr.com Preparer Name: W.M. Barr EHS Department (901)775-0100 CAC18, DAC18, GAC18, GAC718, QAC18, QAC18L, QAC718, QAC18L Synonyms 2. Composition/Information on Ingredients 1000 ppm 500 ppm 750 ppm Hazardous Components (Chemical Name) Acetone 67-64-1 CAS # 100.0 % Concentration OSHA PEL ACGIH TWA ACGIH STEL 1. 3. Hazards Identification Danger! Extremely Flammable. Keep away from heat, sparks, flame and all other sources of ignition. Vapors may cause flash fire or ignite explosively. Vapors may travel long distances to other areas and rooms away from the work site. Do not smoke. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and all other sources of ignition anywhere in the structure, dwelling, or building during use and until all vapors are gone from the work site. Keep away from electrical outlets and switches. Beware of static electricity that may be generated by synthetic clothing and other sources. Emergency Overview This material is classified as hazardous under OSHA regulations. OSHA Regulatory Status: Inhalation Acute Exposure Effects: Vapor harmful. May cause dizziness, headache, watering of eyes, irritation of respiratory tract, drowsiness, nausea, and numbness in fingers, arms and legs. Skin Contact Acute Exposure Effects: May cause drying of skin, and numbness in fingers and arms. Liquid is absorbed readily. Eye Contact Acute Exposure Effects: This material is an eye irritant. Ingestion Acute Exposure Effects: Harmful if swallowed. May cause dizziness, headache, nausea, and irritation of the mouth, throat, and stomach. Chronic Exposure Effects: Reports have associated repeated and prolonged overexposure to solvents with neurological and other Potential Health Effects (Acute and Chronic) Licensed to W.M. Barr and Company ANSI Z400.1 Format Revision: 11/13/2008 Printed: 12/30/2008 Page: 2 Klean-Strip Acetone MATERIAL SAFETY DATA SHEET Supercedes Revision: 03/13/2006 physiological damage. May cause weakness, fatigue, skin irritation, and numbness in hands and feet. Primary Routes of Exposure: Inhalation, ingestion, and dermal. Signs and Symptoms Of Exposure Skin, eye, lung (asthma-like conditions) Medical Conditions Generally Aggravated By Exposure 4. First Aid Measures Inhalation: If user experiences breathing difficulty, move to air free of vapors. Administer oxygen or artificial respiration until medical assistance can be reached. Skin Contact: Wash with soap and water. Eye Contact: Flush with large quantities of water for at least 15 minutes and seek immediate medical attention. Ingestion: Call your poison control center, hospital emergency room, or physician immediately for instructions. Emergency and First Aid Procedures Call your local poison control center for further instructions. Note to Physician 5. Fire Fighting Measures Flammability Classification: Class IB Flash Pt: -4.00 F Method Used: TAG Closed Cup Explosive Limits: LEL: 2.5 % at 77.0 F UEL: 13.0 % at 77.0 F Autoignition Pt: 869.00 F Self-contained respiratory protection should be provided for fire fighters fighting fires in buildings or confined areas. Storage containers exposed to fire should be kept cool with water spray to prevent pressure build-up. Stay away from heads of containers that have been exposed to intense heat or flame. Fire Fighting Instructions Extremely Flammable! Flammable Properties and Hazards carbon monoxide, carbon dioxide Hazardous Combustion Products Use carbon dioxide, dry powder, or foam. Extinguishing Media No data available. Unsuitable Extinguishing Media 6. Accidental Release Measures Clean Up: Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, out of low areas, and ventilate closed spaces before entering. Shut off ignition sources; keep flares, smoking or flames out of hazard area. For small spills, take up liquid with sand, earth, or other noncombustible absorbent material and place in a container for disposal. For large spills, dike far ahead of spill and use sand, earth, or other noncombustible absorbent material and then place material in a container for disposal. Steps To Be Taken In Case Material Is Released Or Spilled Licensed to W.M. Barr and Company ANSI Z400.1 Format Revision: 11/13/2008 Printed: 12/30/2008 Page: 3 Klean-Strip Acetone MATERIAL SAFETY DATA SHEET Supercedes Revision: 03/13/2006 Waste Disposal: Dispose in accordance with applicable local, state, and federal regulations. 7. Handling and Storage Read carefully all cautions and directions on product label before use. Since empty container retains residue, follow all label warnings even after container is empty. Dispose of empty container according to all regulations. Do not reuse the container. Precautions To Be Taken in Handling Keep container tightly closed when not in use. Store in a cool, dry place. Do not store near flames or at elevated temperatures. Precautions To Be Taken in Storing 8. Exposure Controls/Personal Protection For OSHA controlled work place and other regular users. Use only with adequate ventilation under engineered air control systems designed to prevent exceeding appropriate TLV. For occasional use, where engineered air control is not feasible, use properly maintained and properly fitted NIOSH approved respirator for organic solvent vapors. A dust mask does not provide protection against vapors. Respiratory Equipment (Specify Type) Safety glasses, chemical goggles or face shields are recommended to safeguard against potential eye contact, irritation, or injury. Contact lenses should not be worn while working with chemicals. Eye Protection Wear chemical resistant gloves suited for use with acetone. Gloves contaminated with product should be discarded. Promptly remove clothing that becomes soiled with product. Protective Gloves Various application methods can dictate use of additional protective safety equipment, such as impermeable aprons, etc., to minimize exposure. Other Protective Clothing Use only with adequate ventilation to prevent build-up of vapors. Open all windows and doors. Use only with a cross ventilation of moving fresh air across the work area. If strong odor is noticed or your experience slight dizziness, headache, nausea, or eye-watering - STOP - ventilation is inadequate. Leave area immediately. Engineering Controls (Ventilation etc.) A source of clean water should be available in the work area for flushing eyes and skin. Do not eat, drink, or smoke in the work area. Wash hands thoroughly after use. Before reuse, thoroughly clean any clothing or protective equipment that has been contaminated by prior use. Discard any clothing or other protective equipment that cannot be decontaminated, such as gloves or shoes. Work/Hygienic/Maintenance Practices 9. Physical and Chemical Properties Physical States: [ ] Gas [ X ] Liquid [ ] Solid Melting Point: No data. Boiling Point: > 131.00 F Autoignition Pt: 869.00 F Flash Pt: -4.00 F Method Used: TAG Closed Cup Explosive Limits: LEL: 2.5 % at 77.0 F UEL: 13.0 % at 77.0 F Specific Gravity (Water = 1): 0.789 Density: 6.572 LB/GA at 77.0 F Vapor Pressure (vs. Air or mm Hg): 213 MM HG at 77.0 F Licensed to W.M. Barr and Company ANSI Z400.1 Format Revision: 11/13/2008 Printed: 12/30/2008 Page: 4 Klean-Strip Acetone MATERIAL SAFETY DATA SHEET Supercedes Revision: 03/13/2006 Vapor Density (vs. Air = 1): No data. Evaporation Rate (vs Butyl Acetate=1): No data. Solubility in Water: No data. Percent Volatile: 100.0 % by weight. Corrosion Rate: No data. pH: No data. Clear colorless liquid with a characteristic ketone odor. Appearance and Odor 10. Stability and Reactivity Stability: Unstable [ ] Stable [ X ] No data available. Conditions To Avoid - Instability May form explosive mixtures with chromic anhydride, chromyl alcohol, hexachloromelamine, hydrogen peroxide, permonosulfuric acid, potassium tertbutoxide, and thioglycol. Strong oxidizers. Incompatibility - Materials To Avoid Decomposition may produce carbon monoxide, carbon dioxide, and other asphyxiants. Hazardous Decomposition Or Byproducts Hazardous Polymerization: Will occur [ ] Will not occur [ X ] No data available. Conditions To Avoid - Hazardous Polymerization 11. Toxicological Information LD50 Rat oral 10.7 mL/kg (=8450 mg/kg bw); acetone given by gastric intubation to groups of five non-fasted Carworth-Wistar female rats LD50 Rat oral 9800 mg/kg/ bw LD50 Rat oral 5800 mg/kg bw LD50 Mouse oral 3000 mg/kg bw LD50 Rabbit oral 5340 mg/kg bw LC50 Rat inhalation exposure 76 mg/L/4 hr LC50 Rat inhalation 50.1 mg/L/8 hr LD50 Rabbit dermal 20 mg/kg bw LD50 Rabbit dermal 20,000 mg/kg bw LD50 Mouse ip 1,297 mg/kg bw LD50 Rat iv 5500 mg/kg bw LD50 Mouse oral 5.2 g/kg No data available. Carcinogenicity/Other Information n.a. A4 n.a. Hazardous Components (Chemical Name) Acetone 67-64-1 CAS # n.a. NTP IARC ACGIH OSHA 1. 12. Ecological Information No data available. 13. Disposal Considerations Dispose in accordance with applicable local, state and federal regulations. Waste Disposal Method Licensed to W.M. Barr and Company ANSI Z400.1 Format Revision: 11/13/2008 Printed: 12/30/2008 Page: 5 Klean-Strip Acetone MATERIAL SAFETY DATA SHEET Supercedes Revision: 03/13/2006 14. Transport Information LAND TRANSPORT (US DOT) DOT Proper Shipping Name Acetone DOT Hazard Class: 3 DOT Hazard Label: FLAMMABLE LIQUID UN/NA Number: UN1090 Packing Group: II For D.O.T. information, contact W.M. Barr Technical Services at 1-800-398-3892. The supplier may apply one of the following exceptions: Combustible Liquid, Consumer Commodity, Limited Quantity, Viscous Liquid, Does Not Sustain Combustion, or others, as allowed under 49CFR Hazmat Regulations. Please consult 49CFR Subchapter C to ensure that subsequent shipments comply with these exceptions. Additional Transport Information 15. Regulatory Information US EPA SARA Title III Yes 5000 LB No Yes Hazardous Components (Chemical Name) Acetone 67-64-1 CAS # No Sec.302 (EHS) Sec.304 RQ Sec.313 (TRI) Sec.110 1. SARA (Superfund Amendments and Reauthorization Act of 1986) Lists: Sec.302: EPA SARA Title III Section 302 Extremely Hazardous Chemical with TPQ. * indicates 10000LB TPQ if not volatile. Sec.304: EPA SARA Title III Section 304: CERCLA Reportable + Sec.302 with Reportable Quantity. **indicates statutory RQ. Sec.313: EPA SARA Title III Section 313 Toxic Release Inventory. Note: -Cat indicates a member of achemical category. Sec.110: EPA SARA 110 Superfund Site Priority Contaminant ListThis material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated: EPA Hazard Categories: [X] Yes [ ] No Acute (immediate) Health Hazard [ ] Yes [X] No Chronic (delayed) Health Hazard [X] Yes [ ] No Fire Hazard [ ] Yes [X] No Sudden Release of Pressure Hazard [ ] Yes [X] No Reactive Hazard 16. Other Information The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, state and local laws and regulations. Company Policy or Disclaimer Licensed to W.M. Barr and Company ANSI Z400.1 Format |
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